SOUTHERN JOURNAL OF SCIENCES

Background: The desire to create a database of research documents providing information about the tracts of gold deposits across the local geological province provides the impetus for a study of the kind being considered here. Geospatial identification of built-up structures within Phase I Development along the Kazaure-Karaukarau-Kushaka-Ilesha Schist Belt, trending through Minna town and its outlying districts, constitutes the veritable reference material desired in this regard. Methods: This study began by segmenting the area of study for ground-based and remotely sensed attribute mapping, using the key reference map from a previous study as the area-of-study guide. A handheld Garmin GPSmap78® global positioning system unit and a standard smartphone with a built-in camera were the key equipment used for the fieldwork. Polygonal-format georeferenced coordinate information was collected at conveniently detached buildings, beginning with the cluster of residential homes at the Staff Quarters, for the ground-based survey. Result: Nine of the ten built-up structure clusters on the path of the Belt in Phase I Development were mapped for this study, as well as six neighborhoods in the Minna built-up area beyond Phase I. The nine clusters occupy almost 40% of the circa 2 km2 areal extent of the Phase I Development. The belt's trend and structures were north-northeast. Discussion: The nine cluster structures in Phase I and the six neighborhoods of Minna identified in this study have been determined to align with the path of the belt. Conclusion: Having now determined that the trace of the belt exits the Campus at the northern sector of the Gidan Kwano village and trends in a long arc beyond the town, this study becomes the desired reference material to be archived and consulted for information relating to gold exploitation in the Minna Area geological province.

Background: This study explores the potential use of biomass residues from soybean pressing via static pyrolysis to produce carbonaceous materials for pesticide adsorption. It emphasizes concerns regarding the environmental impact of agroindustrial waste and the persistent nature of pesticides in soil and water systems. Aims: To investigate the efficacy of biochar obtained from soybean waste in adsorbing pesticides. Specifically, to analyze the gas products generated during pyrolysis and characterize the obtained carbonaceous material for its adsorption capabilities. Methods: Soybean residue underwent static pyrolysis at various temperatures and durations. Gas analysis utilizing FTIR spectroscopy identified the gaseous products generated during the pyrolysis process. The obtained biochar underwent successive washes and characterization through FTIR spectra comparison with commercial activated carbon. Through absorption assays, using UV-VIS spectroscopy, investigations were conducted on the solid biocarbon fractions to evaluate their capacity for absorbing pesticides. Results: Gas Analysis: The study revealed the production of volatile organic compounds (VOCs) and highlighted the prevalence of mono-carbon compounds with increased temperature and pyrolysis time. The analysis demonstrated consistent carbon mass percentages across different reaction conditions. Characterization of Biochar: Comparison with activated carbon indicated structural similarities with heightened intensity in certain bands, suggesting the presence of incomplete cellulose cracking in the obtained biochar. Regarding the Chlorothalonil, Atrazine and DIcamba remotion, notably, the concentration of Chlorothalonil in a 7:3 water: acetonitrile solution decreases by 77 % through adsorption on the carbons. Discussion: The investigation examined the adsorption efficiency of the biochar for Chlorothalonil, Atrazine, and Dicamba from aqueous solutions. Chlorothalonil exhibited substantial retention by the biochar, while Atrazine showed comparatively lower adsorption effectiveness. Remarkably, Dicamba did not demonstrate retention by either the biochar or activated carbon. Conclusion: The study underscores the potential of pyrolyzed soybean waste for pesticide adsorption, particularly highlighting Chlorothalonil's strong affinity with the carbonaceous structure. Further research is needed to optimize adsorption properties and explores potential enhancements of these materials through additional treatment methods, offering promising avenues for environmental remediation.

Background: The Araucaria angustifolia is a prominent tree species indigenous to the southern regions of Brazil. The tree can be a source of different compounds of interest if properly used. Aims: This research aims to compare the alcoholic extraction of compounds from Araucaria angustifolia using two different methods, microwave-assisted extraction and maceration extraction. Methods: Alcahoolic extractions of compounds from the sawdust of Araucaria angustifolia were performed using microwave-assisted extraction and maceration extraction. The color was observed by eye inspection. The taste was observed by putting the samples into the mouth and tasting it. The olfactive test was conducted at hot and cold temperatures. Results: it was obtained red color solution, both from the bark and from the branch. The intensity of the color changed with the extraction method and time of maceration. The solutions tasted like "green wood". Discussion: MAE and Maceration extraction can provide extracts from the bark and branch of the araucaria tree. There is the possibility that the “green wood” taste of the MAE extract can be changed with the thermal treatment of the wood. Conclusions: microwave-assisted extraction can perform the faster extraction of compounds from Araucaria angustifolia than maceration extraction.